List of Incompatible Chemicals

Incompatible chemicals are two or more compounds that cannot be combined because they will react and generate unsafe or hazardous circumstances. Incompatible chemical reactions can result in flames, explosions, poisonous gases, or other risks that can hurt people or damage equipment. Understanding which chemicals are incompatible with one another is critical for maintaining a safe workplace, preventing accidents, and assuring correct chemical handling, storage, and disposal.

Here are some of the factors that can cause chemicals to be incompatible with each other:
  1. Chemical reactions: Some substances can react with one another, resulting in potentially harmful reactions. Acids and bases, for example, can react to generate heat, hazardous fumes, or explosions. Oxidizers can create flames when they react with flammable materials.
  2. Incompatibility: Some compounds may have physical features that make them incompatible with others. Some compounds, for example, may be incompatible due to differences in density, boiling temperature, or solubility. When these compounds are mixed, they can separate, precipitate, or change phase, which can lead to dangerous circumstances.
  3. Temperature sensitivity: Some substances are temperature sensitive and can degrade or react when exposed to high or low temperatures. Some compounds, for example, degrade when exposed to heat or light, whilst others become unstable when exposed to low temperatures.
  4. Shock or friction sensitivity: Some compounds are sensitive to shock or friction and can detonate when exposed to these conditions. Some chemicals, for example, can explode when dropped, struck, or come into touch with other objects.
  5. Container incompatibility: Some chemicals may be incompatible with specific storage containers or materials. Some chemicals, for example, can corrode or dissolve plastic containers, whilst others may react with metal containers.


To minimize mishaps and maintain a safe workplace, it is critical to correctly identify and label incompatible chemicals, store them separately, and avoid mixing them together. It is also critical to use proper safety precautions while handling, storing, and disposing of incompatible substances. Finally, it is critical to stay current on safety legislation, training, and best practices for chemical handling in the workplace.

CHEMICAL

TO BE KEPT OUT OF CONTACT WITH

Acetic acid

Chromic acid, Nitric acid, Hydroxyl compounds, ethylene, Glycol, Perchloric acid, Peroxides, and Permanganates.

Acetylene

Chlorine, Bromine, Copper, Fluorine, Silver, Mercury

Metals (powdered aluminum, Magnesium, Sodium or Potassium)

Carbon Tetrachloride or other chlorinated

Hydrocarbons, Carbon dioxide, and Halogens.

Ammonia

Mercury (in Manometers for instance) Chlorine, Iodine, Bromine, Hydrofluoric acid (G)

Ammonium Nitrate

Acids, Metal Powders, Flammable Liquids, Chlorates, Nitrates, Finely divided organic or combustible materials.

Aniline

Nitric acid, hydrogen peroxide

Bromine

Ammonia, Acetylene, Benzene, Finely divided metals

Chromic Acid

Acetic acid, Glycerin, Alcohol, Methanol, and Flammable Liquids in general.

Hydrogen peroxide

Copper, Chromium, Iron, Most metals and their Salts, Alcohol, Acetone, Organic materials, Aniline, Flammable liquids, and Combustible materials.

Iodine

Acetylene, Ammonia (Aqueous and Gas) Hydrogen

Mercury

Acetylene, Ammonia

Cons. Nitric acid

Acetic acid, Aniline, Chromic acid, flammable liquids and gases

Oxalic acid

Mercury

Perchloric acid

Acetic anhydride, alcohol, paper, wood.

Potassium permanganate

Glycerin, Ethylene Glycol, Benzaldehyde, Sulphuric acid

Sodium

Water, carbon tetrachloride, carbon dioxide

Sulphuric acid

Potassium permanganate and compounds of similar light metals such as sodium




Oxidizing

Substances that give rise to highly exothermic reactions in contact with other substances, particularly flammable substances.


Flammable

Extremely flammable liquids have a flash point less than 0C and a boiling point less than or equal to 35°C.


Harmful and irritant

Substances that present moderate risks to health by inhalation, ingestion or skin absorption, inhalation, ingestion or skin absorption.  Substances that are non-corrosive but are liable to cause inflammation through immediate prolonged or repeated contact with the skin or mucous membranes.


Explosive

Substances that may explode under the effect of flame or heat or which are more sensitive to the shock of friction than dinitrobenzene. 


Toxic

Substances that present a serious risk of acute or chronic poisoning by inhalation ingestion or skin absorption.


Corrosive

Substances that destroy living tissue


Dangerous to the environment

The substance that, were they to enter into an environment, would present or might present an immediate or delayed danger for one or more components of the environment.


ALSO READ: SOP for Handling of Chemicals and Reagents

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